陶瓷/纤维增强树脂基复合材料界面模拟研究进展

周少兰, 张鑫, 周长征, 冉旭东, 韦禹, 刘博, 李鹏, 郭峰, 聂嘉兴

装备环境工程 ›› 2026, Vol. 23 ›› Issue (2) : 33-42.

PDF(7526 KB)
PDF(7526 KB)
装备环境工程 ›› 2026, Vol. 23 ›› Issue (2) : 33-42. DOI: 10.7643/ issn.1672-9242.2026.02.005
武器装备

陶瓷/纤维增强树脂基复合材料界面模拟研究进展

  • 周少兰1, 张鑫1, 周长征2, 冉旭东1, 韦禹1,*, 刘博1, 李鹏1, 郭峰1, 聂嘉兴1
作者信息 +

Research Progress of Interface Simulation of Ceramic/Fiber Reinforced Resin Matrix Composites

  • ZHOU Shaolan1, ZHANG Xin1, ZHOU Changzheng2, RAN Xudong1, WEI Yu1,*, LIU Bo1, LI Peng1, GUO Feng1, NIE Jiaxing1
Author information +
文章历史 +

摘要

综述了陶瓷/纤维增强树脂基复合材料界面多尺度模拟的研究进展。首先,阐述了界面在复合材料中的关键作用,包括其在载荷传递、增强相协同效应、裂纹扩展行为以及应力与热失配缓冲等方面的功能特性。其次,梳理了界面形成的基本理论,如机械嵌合、化学键与界面润湿理论,并指出单一理论在解释复杂界面现象时的局限性。在此基础上,重点分析了多尺度模拟方法在界面研究中的应用。在微观尺度上,分子动力学模拟揭示了界面相互作用的原子机制与表面改性机理;在介观尺度上,相场法有效模拟了界面损伤演化与裂纹扩展路径;在宏观尺度上,有限元方法评估了结构在冲击载荷下的整体响应与能量吸收性能。进一步指出了当前多尺度模拟研究仍存在参数传递机制缺失及实验验证不足等问题。最后,对未来发展方向进行了展望,提出应致力于发展跨尺度紧密耦合的模型框架,推动模拟与实验的深度融合,并探索人工智能辅助的建模策略,为实现复合材料界面的精准设计与性能调控提供理论支撑。

Abstract

The work aims to review research progress in multi-scale simulation of interfaces in ceramic/fiber-reinforced resin matrix composites. First, it elucidated the critical role of interfaces in composites, including their functional characteristics in load transfer, synergistic effects of reinforcing phases, crack propagation behaviors, and buffering of stress and thermal mismatch. Second, it reviewed fundamental theories of interface formation, such as mechanical interlocking, chemical bonding, and interfacial wetting, while highlighting the limitations of any single theory in explaining complex interface phenomena. Building on this foundation, the paper focused on analyzing the application of multi-scale simulation methods in interfacial research. At the microscopic scale, molecular dynamics simulations revealed atomic-level mechanisms of interfacial interactions and surface modification; At the mesoscale, phase-field methods were applied to effectively simulate interfacial damage evolution and crack propagation paths; At the macroscale, finite element methods are applied to evaluate the overall response and energy absorption performance of structures under impact loading. It further highlighted existing challenges in current multiscale simulation research, including the absence of parameter transfer mechanisms and insufficient experimental validation. Finally, it outlined future development directions, proposing efforts to develop tightly coupled multi-scale modeling frameworks, promoted deeper integration between simulation and experimentation, and explored AI-assisted modeling strategies. These approaches provide theoretical support for achieving precise design and performance regulation of composite material interfaces.

关键词

陶瓷/纤维复合材料 / 界面模拟 / 多尺度模拟 / 分子动力学 / 相场法 / 有限元

Key words

ceramic/fiber composites / interface simulation / multi-scale simulation / molecular dynamics / phase field method / finite element

引用本文

导出引用
周少兰, 张鑫, 周长征, 冉旭东, 韦禹, 刘博, 李鹏, 郭峰, 聂嘉兴. 陶瓷/纤维增强树脂基复合材料界面模拟研究进展[J]. 装备环境工程. 2026, 23(2): 33-42 https://doi.org/10.7643/ issn.1672-9242.2026.02.005
ZHOU Shaolan, ZHANG Xin, ZHOU Changzheng, RAN Xudong, WEI Yu, LIU Bo, LI Peng, GUO Feng, NIE Jiaxing. Research Progress of Interface Simulation of Ceramic/Fiber Reinforced Resin Matrix Composites[J]. Equipment Environmental Engineering. 2026, 23(2): 33-42 https://doi.org/10.7643/ issn.1672-9242.2026.02.005
中图分类号: TJ04   

参考文献

[1] YUAN X M, ZHANG Z H, MU X Y, et al.Recent Progress on Interface Characterization Methods of Carbon Fiber Reinforced Polymer Composites[J]. Chemical Engineering Journal, 2024, 499: 156220.
[2] TAN M T, ZHANG X F, XIONG W, et al.Influence of Layered back Plate on the Ballistic Performance of Ceramic Armor[J]. Composite Structures, 2023, 308: 116688.
[3] YUE Y J, SONG G J, LI L, et al.Collaborative Improvement of Interfacial Properties of Carbon Fiber/Epoxy Resin Composites through Modulus/Toughness Matching and Gradient Interface[J]. Composites Part B: Engineering, 2025, 298: 112398.
[4] BÜYÜKÖZTÜRK O, BUEHLER M J, LAU D, et al. Structural Solution Using Molecular Dynamics: Fundamentals and a Case Study of Epoxy-Silica Interface[J]. International Journal of Solids and Structures, 2011, 48(14/15): 2131-2140.
[5] WANG X Q, AWAN I S, CHEN G Y, et al.Molecular Dynamics Simulations of Interfacial Adhesion between Carbon Fibers and Various Epoxies/Hardeners and Its Calorimetric Validation[J]. Journal of Composite Materials, 2013, 47(8): 1011-1017.
[6] PISAVADIA H, TOUSSAINT G, DOLEZ P, et al.Cohesive Zone Failure Modeling of Polymeric Adhesives Used in Ceramic/Metal Armor[J]. International Journal of Impact Engineering, 2022, 170: 104364.
[7] MIA R, SULTANA S, BHUIYAN M S K, et al. Improving Ballistic Performance of Kevlar Fabrics by Resin Treatment[J]. The Journal of the Textile Institute, 2022, 113(8): 1603-1626.
[8] RANI E, INGALE A A, SINHA A K.Effect of External Stimulus on Polymer Conformation in CDS-PVP Nanocomposites: Raman, PL, and AFM Mapping Study[J]. Journal of Materials Science, 2022, 57(6): 4118-4129.
[9] BAO Q G, WANG D H, YAN X M, et al.A High-Temperature Resistant and Chemically Compatible Water-Soluble Sizing Agent for Improving the Interfacial Properties of Short Carbon Fiber Reinforced Polyphthalazine Ether Ketone Composites[J]. Composites Part A: Applied Science and Manufacturing, 2026, 200: 109270.
[10] YU Z C, ZHOU A, NING W Y, et al.Molecular Insights into the Weakening Effect of Water on Cement/Epoxy Interface[J]. Applied Surface Science, 2021, 553: 149493.
[11] TAM L H, HE L, WU C.Molecular Dynamics Study on the Effect of Salt Environment on Interfacial Structure, Stress, and Adhesion of Carbon Fiber/Epoxy Interface[J]. Composite Interfaces, 2019, 26(5): 431-447.
[12] LIU L, LIU S G, SONG X M, et al.Effect of Nd: YAG Laser Irradiation on Surface Properties and Bond Strength of Zirconia Ceramics[J]. Lasers in Medical Science, 2015, 30(2): 627-634.
[13] PITARRESI G, TOSCANO A, ALESSI S.Fracture Toughness of Synthesised High-Performance Epoxies Subject to Accelerated Water Aging[J]. Polymer Testing, 2018, 68: 248-260.
[14] DEMIRCI M T, TARAKÇıOĞLU N, AVCı A, et al. Fracture Toughness (Mode I) Characterization of SiO2 Nanoparticle Filled Basalt/Epoxy Filament Wound Composite Ring with Split-Disk Test Method[J]. Composites Part B: Engineering, 2017, 119: 114-124.
[15] ZHU C K, LI S H, CONG X Y, et al.Effect of Silane Coupling Agent on the Properties of Recycled Carbon Fibers Reinforced Bio-Based Epoxy Composites[J]. Fibers and Polymers, 2021, 22(7): 1976-1985.
[16] TOPTAN F, KILICARSLAN A, KERTI I. The Effect of Ti Addition on the Properties of Al-B4C Interface: A Microstructural Study[J]. Materials Science Forum, 2010, 636/637: 192-197.
[17] CHEN R S, MUHAMMAD Y H, AHMAD S.Physical, Mechanical and Environmental Stress Cracking Characteristics of Epoxy/Glass Fiber Composites: Effect of Matrix/Fiber Modification and Fiber Loading[J]. Polymer Testing, 2021, 96: 107088.
[18] XU X X, YANG X J, LI M J, et al.Resin Impregnation and Interface Property Improvement of CFRP Composite via Modulating Wettability of Carbon Fibers[J]. Journal of Composite Materials, 2025, 59(1): 61-74.
[19] WU Q, BAI H H, DENG H, et al.Intermittent Carbon Nanotube Encapsulation of Carbon Fiber: A Facile and Efficient Strategy to Simultaneously Strengthen and Toughen Interphase of Composites[J]. Composites Part B: Engineering, 2022, 235: 109785.
[20] QIN J J, WANG C G, YAO Z Q, et al.Growing Carbon Nanotubes on Continuous Carbon Fibers to Produce Composites with Improved Interfacial Properties: A Step towards Commercial Production and Application[J]. Composites Science and Technology, 2021, 211: 108870.
[21] WANG D B, WANG X W, HAN K Y, et al.Effects of Reactive Diluent on Processing, Structure, and Properties of Epoxy Foams and Their Sandwich Composites[J]. Polymer Engineering & Science, 2024, 64(5): 2073-2081.
[22] QIU B W, QIU B L, SUN T, et al.Constructing a Multiscale Rigid-Flexible Interfacial Structure at the Interphase by Hydrogen Bonding to Improve the Interfacial Performance of High Modulus Carbon Fiber Reinforced Polymer Composites[J]. Composites Science and Technology, 2022, 229: 109672.
[23] JI M, LI M Y, CHEN H, et al.Macroscale Superlubricity Composites with Self-Healing Functions[J]. Advanced Functional Materials, 2025, 10: e20143.
[24] MORI K, MATSUMOTO N, YABE M, et al.Tensile Test Analysis of Carbon Fiber Composite Material by Molecular Dynamics Simulation[J]. Advanced Composite Materials, 2020, 29(2): 179-190.
[25] TAM L H, JIANG J Q, YU Z C, et al.Molecular Dynamics Investigation on the Interfacial Shear Creep between Carbon Fiber and Epoxy Matrix[J]. Applied Surface Science, 2021, 537: 148013.
[26] STOFFELS M T, STAIGER M P, BISHOP C M.Reduced Interfacial Adhesion in Glass Fibre-Epoxy Composites Due to Water Absorption via Molecular Dynamics Simulations[J]. Composites Part A: Applied Science and Manufacturing, 2019, 118: 99-105.
[27] NIUCHI T, KOYANAGI J, INOUE R, et al.Molecular Dynamics Study of the Interfacial Strength between Carbon Fiber and Phenolic Resin[J]. Advanced Composite Materials, 2017, 26(6): 569-581.
[28] WANG L, ZHENG C S, LIU Y P, et al.A Multiscale Framework for Composites Considering Interphase Based on Molecular Dynamics and Finite Element Method[J]. Advanced Composite Materials, 2023, 32(4): 551-567.
[29] WANG H, JIN K, TAO J.Improving the Interfacial Shear Strength of Carbon Fibre and Epoxy via Mechanical Interlocking Effect[J]. Composites Science and Technology, 2020, 200: 108423.
[30] JIAO W W, ZHENG T L, LIU W B, et al.Molecular Dynamics Simulations of the Effect of Sizing Agent on the Interface Property in Carbon Fiber Reinforced Vinyl Ester Resin Composite[J]. Applied Surface Science, 2019, 479: 1192-1199.
[31] GOGOI R, SETHI S K, MANIK G.Surface Functionalization and CNT Coating Induced Improved Interfacial Interactions of Carbon Fiber with Polypropylene Matrix: A Molecular Dynamics Study[J]. Applied Surface Science, 2021, 539: 148162.
[32] YAN Y S, XU J B, ZHU H J, et al.Molecular Dynamics Simulation of the Interface Properties of Continuous Carbon Fiber/Polyimide Composites[J]. Applied Surface Science, 2021, 563: 150370.
[33] PAN L, GUO H X, ZHONG L, et al.Influence of Surface-Modified Glass Fibers on Interfacial Properties of GF/PEEK Composites Using Molecular Dynamics[J]. Computational Materials Science, 2021, 188: 110216.
[34] ERNESTI F, SCHNEIDER M, BÖHLKE T. Fast Implicit Solvers for Phase-Field Fracture Problems on Heterogeneous Microstructures[J]. Computer Methods in Applied Mechanics and Engineering, 2020, 363: 112793.
[35] BLEYER J, ALESSI R.Phase-Field Modeling of Anisotropic Brittle Fracture Including Several Damage Mechanisms[J]. Computer Methods in Applied Mechanics and Engineering, 2018, 336: 213-236.
[36] DEAN A, ASUR VIJAYA KUMAR P K, REINOSO J, et al. A Multi Phase-Field Fracture Model for Long Fiber Reinforced Composites Based on the Puck Theory of Failure[J]. Composite Structures, 2020, 251: 112446.
[37] ZHANG P, HU X F, YANG S T, et al.Modelling Progressive Failure in Multi-Phase Materials Using a Phase Field Method[J]. Engineering Fracture Mechanics, 2019, 209: 105-124.
[38] ZHANG P, HU X F, BUI T Q, et al.Phase Field Modeling of Fracture in Fiber Reinforced Composite Laminate[J]. International Journal of Mechanical Sciences, 2019, 161: 105008.
[39] HIRSHIKESH, NATARAJAN S, ANNABATTULA R K.Modeling Crack Propagation in Variable Stiffness Composite Laminates Using the Phase Field Method[J]. Composite Structures, 2019, 209: 424-433.
[40] TAN W, MARTÍNEZ-PAÑEDA E. Phase Field Predictions of Microscopic Fracture and R-Curve Behaviour of Fibre-Reinforced Composites[J]. Composites Science and Technology, 2021, 202: 108539.
[41] CHABERA P, BOCZKOWSKA A, WITEK A, et al.Fabrication and Characterization of Composite Materials Based on Porous Ceramic Preform Infiltrated by Elastomer[J]. Bulletin of the Polish Academy of Sciences Technical Sciences, 2015, 63(1): 193-199.
[42] CHABERA P, BOCZKOWSKA A, MORKA A, et al.Comparison of Numerical and Experimental Study of Armour System Based on Alumina and Silicon Carbide Ceramics[J]. Bulletin of the Polish Academy of Sciences Technical Sciences, 2015, 63(2): 363-367.
[43] 王东哲, 秦溶蔓, 孙娜, 等. 陶瓷/纤维复合装甲抗弹丸侵彻性能的试验与数值模拟研究[J]. 材料导报, 2021, 35(18): 18216-18221.
WANG D Z, QIN R M, SUN N, et al.Experimental and Numerical Simulation Study on Anti-Projectile Penetration Performance of Ceramic/Fiber Composite Armor[J]. Materials Review, 2021, 35(18): 18216-18221.
[44] 秦溶蔓, 朱波, 乔琨, 等. 陶瓷/纤维复合材料层间混杂结构对装甲板抗侵彻性能的影响[J]. 材料导报, 2020, 34(18): 18183-18187.
QIN R M, ZHU B, QIAO K, et al.Effect of Hybrid Structure of Ceramic/Fiber Composite Material on Penetration Resistance of Armor Plate[J]. Materials Review, 2020, 34(18): 18183-18187.
[45] 谭小辉, 张兴金, 冯立华, 等. 陶瓷复合装甲弹道极限速度与抗重复打击性能研究[J]. 弹道学报, 2023, 35(4): 88-96.
TAN X H, ZHANG X J, FENG L H, et al.Research on the Ballistic Limit Velocity and Resistance to Repeated Impacts of Ceramic Composite[J]. Journal of Ballistics, 2023, 35(4): 88-96.
[46] LI F Q, HUANG J R, LIU R H, et al.Numerical Simulation of Anti-Penetration Performance of Ceramic/Aramid Fiber/PE-UHMW Composite Armor[J]. Journal of Physics: Conference Series, 2023, 2478(7): 072034.

PDF(7526 KB)

Accesses

Citation

Detail

段落导航
相关文章

/